14β-Hydroxygelsedine, a New Oxindole Alkaloid from Gelsemium sempervirens

Abstract
An extract of the stem of Gelsemium sempervirens has afforded a new oxindole alkaloid, 14.beta.-hydroxygelsedine, whose structure and stereochemistry were deduced by spectral methods, principally high resolution 1H nmr, 2-D-COSY, and decoupling experiments.

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