ortho-Metallation reactions. Part IV. Reactions of benzylideneaniline and benzylidenemethylamine
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 1787-1791
- https://doi.org/10.1039/dt9720001787
Abstract
Reactions between benzylideneaniline (bzaH) or benzylidenemethylamine (bzmH) and MeM(CO)5(M = Mn or Re), PdCl2, Ru3(CO)12, or [Ru(CO)3Cl2]2, have afforded complexes containing ortho-metallated bza or bzm ligands. With [Rh(CO)2Cl]2 a variety of derivatives, including the rhodium(I)–rhodium(III) complex (bza)2Rh-µ-Cl2Rh(CO)2, and [(amine) Rh(CO)2Cl](amine = PhNH2 or bzmH), are formed.Keywords
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