Experimental thermal diffusion factors for 20Ne–22Ne and their application as a test of the neon interatomic potential
- 1 May 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (9) , 3684-3689
- https://doi.org/10.1063/1.1681589
Abstract
The thermal diffusion factor of 20Ne–22Ne was measured from approximately 200 to 900°K in a 20‐tube trennschaukel. The results of previous workers were examined in detail, and those considered the most reliable were combined with the present data and fitted to a polynomial in powers of T1/2. The resulting expression represents existing thermal diffusion data from 75 to 1200°K with an average standard deviation of ±3.1%. Eighteen intermolecular potentials for neon of various functional forms were investigated, but none were found that produced a satisfactory theoretical value for αT over the entire temperature range.Keywords
This publication has 36 references indexed in Scilit:
- Tables of collision integrals for the Barker-Pompe, Barker-Fisher-Watts, and Parson-Siska-Lee inert gas potentialsThe Journal of Chemical Physics, 1973
- Isotopic thermal diffusion factors of Ne, Ar, Kr, and Xe from column measurementsThe Journal of Chemical Physics, 1973
- An extended law of corresponding states for the equilibrium and transport properties of the noble gasesPhysica, 1972
- High-temperature isotopic thermal diffusion of neonPhysica, 1972
- Transport and equilibrium properties of simple gases and forces between like and unlike atomsPhysica, 1971
- Lattice Dynamics with Three-Body Forces: ArgonPhysical Review B, 1970
- Exp-6 Cell Model Calculations for the Inert Gas Solids. II. Thermodynamic Properties—The Effect of the Triple-Dipole TermThe Journal of Chemical Physics, 1970
- Evaluation of Transport Properties of Gases: The Bruch–McGee Potential for HeliumThe Journal of Chemical Physics, 1969
- Thermal-Diffusion Factors for the Neon–Xenon SystemThe Journal of Chemical Physics, 1969
- Experimental and theoretical thermal diffusion factors in gaseous mixtures: III. Ternary mixturesPhysica, 1960