Synthesis, luminescence and electrochemistry of novel pentanuclear rhenium(I)–copper(I) mixed-metal acetylide complexes. X-Ray crystal structure of [Cu3(μ-dppm)3{μ3-η1-CCC6H4CC-p–Re(bpy)(CO)3}2]+
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 777-778
- https://doi.org/10.1039/a708989i
Abstract
A series of luminescent mixed-metal acetylide complexes [Cu3(µ-LL)3{µ3-η1-CC–C6H2R2-2,5–CC-p–Re(NN)(CO)3}2]+, (LL = dppm, PrnPNP; NN = bpy, But 2bpy; R = H, Me) have been synthesized and their electrochemical properties studied; the X-ray crystal structure of [Cu3(µ-dppm)3{µ3-η1-CC–C6H4CC-p–Re(bpy)(CO)3}2]+ has also been determined.Keywords
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