Hydrogenation by cyanocobaltate. Part III. Kinetic and deuterium tracer studies of the mechanism of the hydrogenation of trans-1-phenylbuta-1,3-diene catalysed by pentacyanocobaltate(II)
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 1813-1818
- https://doi.org/10.1039/dt9730001813
Abstract
Hydrogenation of trans-1-phenylbuta-1,3-diene by pentacyanocobaltate has been studied in water, glycerol–methanol, and ethylene glycol–water. Kinetic and deuterium tracer studies have confirmed that the hydrogenation proceeds by a mechanism involving organocobalt intermediates. It has been concluded that the hydrogenation by pentacyanocobaltate involves intermediates whose structure depends on the solvent as well as the olefin substrate.Keywords
This publication has 0 references indexed in Scilit: