Manganese(III) amide complexes as a new class of catalyst for efficient alkene epoxidation
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1443-1444
- https://doi.org/10.1039/c39860001443
Abstract
Complexation of 1,2-bis(pyridine-2-carboxamido)benzene (H2bpb) and 1,2-bis(pyridine-2-carboxamido)-4,5-dichloro-benzene (H2bpcb) with manganese(III) yielded [MnIII(bpb)Cl], [MnIII(bpb)(N3)], and [MnIII(bpcb)Cl]; the manganese(III) complexes have been found to catalyse the expoxidation of alkenes in the presence of PhlO.Keywords
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