Organoaluminium compounds. XVIII. Mechanism of methyl group exchange between trimethylaluminium and dimethyl(phenylethynyl)aluminium
- 1 January 1968
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 21 (11) , 2687-2693
- https://doi.org/10.1071/ch9682687
Abstract
The exchange of methyl groups between trimethylaluminium and dimethyl- (phenylethyny1)aluminium has been studied by proton magnetic resonance spectro- scopy. The kinetics indicate that a monomer of trimethylaluminium attacks a dimer of dimethyl(phenylethynyl)aluminium in the rate-determining step.Keywords
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