Synthetic Studies Towards Milbemycin β3. Rapid Construction of a Model Spiroketal Subunit Using the Intramolecular Silyl Modified Sakurai (ISMS) Methodology
- 1 January 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (01) , 123-126
- https://doi.org/10.1055/s-1995-4858
Abstract
The ISMS condensation between allyl silane 3 and ortholactone 13 smoothly leads, after oxidative cleavage and stereoselective reduction, to spiroketal 2b, a model for the subunit present in milbemycin β3.Keywords
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