Über eine Reaktion vono-Hydroxybenzylalkoholen mit Estern von Säuren des Phosphors mit der Koordinationszahl 3
- 1 September 1978
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 5 (1) , 123-125
- https://doi.org/10.1080/03086647808069874
Abstract
o-Hydroxybenzyl alcohol reacts with trimethyl phosphite under smooth conditions to o-hydroxyphenylmethane phosphonic acid dimethyl ester. This unusual reaction is of widest applicability. Derivatives of o-hydroxybenzyl alcohol independent of type, number or position of substituents in the ring, react with alkyl esters of phosphorous, phosphonous or phosphinous acids in an analogous process, forming the corresponding o-hydroxyphenylmethane phosphonic or phosphinic esters or phosphine oxides.Keywords
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