Molecular force field for bromine pentafluoride
- 15 July 1968
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 46 (14) , 2393-2397
- https://doi.org/10.1139/v68-391
Abstract
An attempt has been made to study the influence of lone pair electrons on the potential constants of BrF5 with a modified Urey–Bradley force field. It is found that the lone pair – bond pair repulsion is greater than the bond pair – bond pair repulsion. It is also concluded from a study of other molecules containing halogen atoms that the ratio of lone pair – bond pair interaction to bond pair – bond pair interaction is very nearly 1.23.Keywords
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