Scaling theory of pore growth in a reactive solid
- 1 August 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 34 (3) , 1754-1761
- https://doi.org/10.1103/physrevb.34.1754
Abstract
Pores in a reactive solid are modeled as a randomly selected fraction p of the bonds of a lattice. Solid bonds adjacent to the open porosity are consumed, leading to the opening of previously closed pores. Just above the pore percolation threshold , exact analysis of the Bethe lattice indicates that the solid is consumed in a time ∼ln[ln(1/ε)], where ε=p-. A scaling argument, supported by computational results, gives ∼ln(1/ε) for finite-dimensional lattices. Aspects of the time-varying morphology of the solid are examined analytically and computationally.
Keywords
This publication has 16 references indexed in Scilit:
- Percolation concepts in modelling of gas-solid reactions—II. Application to char gasification in the diffusion regimeChemical Engineering Science, 1986
- Percolation concepts in modelling of gas-solid reactions—I. Application to char gasification in the kinetic regimeChemical Engineering Science, 1986
- Fractal structures from an evaporation/condensation modelThe Journal of Chemical Physics, 1985
- Differences between Lattice and Continuum Percolation Transport ExponentsPhysical Review Letters, 1985
- Estimation of effective transport coefficients in porous solids based on percolation conceptsChemical Engineering Science, 1985
- Reaction and transport in disordered composite media: Introduction of percolation conceptsChemical Engineering Science, 1982
- A random capillary model with application to char gasification at chemically controlled ratesAIChE Journal, 1980
- Scaling theory of percolation clustersPhysics Reports, 1979
- Critical phenomena in resistor networksJournal of Physics C: Solid State Physics, 1976
- Some Cluster Size and Percolation ProblemsJournal of Mathematical Physics, 1961