A Convenient Procedure for Dissolving Metal Reductions
- 1 June 1989
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 19 (9) , 1471-1478
- https://doi.org/10.1080/00397918908051039
Abstract
Alicyclic α,β-unsaturated ketones react with lithium in ethylenediamine, followed by Jones oxidation, to give cyclic ketones in good yield. The stereoselectivity at the β position parallels that observed with lithium in liquid ammonia.Keywords
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