The 4α-demethylation of lanostenone
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 6,p. 1599-1601
- https://doi.org/10.1039/p19880001599
Abstract
Cyclopalladiation of lanostenone oxime occurs at the equatorial 4α-methyl group. Oxidation of the acetate of this complex with Pb(OAc)4 forms the 4α-acetoxymethyl compound which on reduction and hydrolysis yields 4β-demethyl-lanostenone.This publication has 0 references indexed in Scilit: