Relative nucleophilicity of thiols and glutathione towards benzene oxide
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 113-114
- https://doi.org/10.1039/c39740000113
Abstract
The slope (β) of a Brönsted plot of the microscopic pKa values of the -SH function of a series of ionic species vs. the logarithm of the second-order rate constants for reaction of each species with benzene oxide is 0.22 indicating an early transition state.Keywords
This publication has 0 references indexed in Scilit: