A new type of catalysis by copper(I) salts in the Barbier-type aldehyde allylation with tin(II) chloride. Short syntheses of (±)-lavandulol and its γ, δ-dihydro derivative
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 277-278
- https://doi.org/10.1039/c39940000277
Abstract
Copper(I) halides and cyanide catalyse the Barbier-type aldehyde allylation with allylation with allylic bromides, chlorides or sulfonates and tin(II) chloride enabling the reaction to take place under very mild conditions with high efficiency.Keywords
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