Some penta- and hexa-co-ordinate complexes of iron(II) with a tetratertiary phosphine
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 627-629
- https://doi.org/10.1039/j19670000627
Abstract
The tetratertiary phosphine tris-(o-diphenylphosphinophenyl)phosphine, QP, forms iron(II) complexes [FeX(QP)]+(X = Cl, Br, and I) which are pentaco-ordinate, have µeff. values of about 3 B.M., and have been assigned trigonal bipyramidal structure, and also [FeX2(QP)](X = NCS and CN) which are hexaco-ordinate and diamagnetic.Keywords
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