UNUSUAL DIRECTION OF THE ARBUZOV REACTION OF DIALKOXYMETHYLPHOSPHONITES AND THEIR ANALOGUES

1 February 1988

journal article
research article
Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements

Vol. 35 (3-4) , 329-334
https://doi.org/10.1080/03086648808074337

Abstract

The alkylation and acylation reactions of dialkoxymethylphosphonites and their analogues have been studied. The Arbuzov rearrangement of these compounds was accompanied by the P[sbnd]C bond cleavage with retention of three-coordinate phosphorus atom.

Keywords

REARRANGEMENT
ALKYLATION
ACYLATION
RETENTION
BOND
CLEAVAGE
COMPOUNDS
COORDINATE
UNUSUAL
ARBUZOV

This publication has 1 reference indexed in Scilit:

Zur Reaktion der Diphosphine R₂P-PR₂ mit Metallorganylen
Zeitschrift für anorganische und allgemeine Chemie, 1964