Hydrogen bonding and perhalometallate ions: A supramolecular synthetic strategy for new inorganic materials
- 16 April 2002
- journal article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 99 (8) , 4956-4961
- https://doi.org/10.1073/pnas.072623399
Abstract
A synthetic strategy for constructing ionic hydrogen-bonded materials by combining perhalometallate anions with cations able to serve as hydrogen bond donors is presented. The approach is based on identification of well defined hydrogen bond acceptor sites on the anions by a combination of experimental and theoretical approaches. Selective population of these sites by hydrogen bond donors has the potential to afford organized crystalline arrays in one, two, or three dimensions. The approach is applicable to a wide range of metal centers.Keywords
This publication has 20 references indexed in Scilit:
- Dimensional Reduction: A Practical Formalism for Manipulating Solid StructuresChemistry of Materials, 2001
- Homologous families of chloride-rich 4,4′-bipyridinium salt structuresChemical Communications, 2001
- Templating and structural engineering in organic–inorganic perovskitesJ. Chem. Soc., Dalton Trans., 2000
- Organic–inorganic hybrid solids: control of perhalometallate solid state structures †J. Chem. Soc., Dalton Trans., 2000
- Halogenometalates with N-containing organic cations structural chemistry and thermal behaviorProgress in Solid State Chemistry, 1999
- Fluoride ligands exhibit marked departures from the hydrogen bond acceptor behavior of their heavier halogen congenersNew Journal of Chemistry, 1999
- Self-Assembly of 1-D Chains of Different Topologies Using the Hydrogen-Bonded Inorganic Supramolecular Synthons N−H···Cl2M or N−H···Cl3MInorganic Chemistry, 1998
- Supramolecular Synthons in Crystal Engineering—A New Organic SynthesisAngewandte Chemie International Edition in English, 1995
- Fully optimized contracted Gaussian basis sets for atoms Li to KrThe Journal of Chemical Physics, 1992
- Medium-size polarized basis sets for high-level-correlated calculations of molecular electric propertiesTheoretical Chemistry Accounts, 1991