Structure–activity relationship for quantifying aromatic interactions†
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 775-776
- https://doi.org/10.1039/a800567b
Abstract
The magnitudes of a range of intermolecular edge-to-face aromatic interactions are measured using chemical double mutant cycles in synthetic H-bonded molecular zipper complexes, and good correlations are obtained with the Hammett substituent constants, suggesting that the results can be extrapolated to other functional group combinations.Keywords
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