Quantum interference in resonant Raman spectra of I2 in condensed media
- 1 April 1997
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 106 (13) , 5775-5778
- https://doi.org/10.1063/1.473596
Abstract
Both B( 3 Π u0 ) and B ′′ ( 1 Π 1u ) surfaces contribute to resonance Raman scattering of iodine, and the interference between these two channels leads to modulation of the intensity profile of overtone progressions, as observed experimentally. The effect is simulated through mixed order semiclassical molecular dynamics.Keywords
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