X-Ray crystallographic determination of the molecular structure of bis-(µ-NN-dimethylthiocarbamoyl)-bis[chloro(trimethyl phosphite)palladium(II)]

Abstract
An X-ray crystallographic investigation of the complex dimer, [(MeO)3P]2Pd2(Cl)2(CSNMe)2, revealed two bridging C(S)NMe2 ligands which link the two Pd atoms by co-ordinating through the C and S atoms; this is the first example of a metal complex containing thiocarbamoyl bridging ligands.

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