Ruthenium-Catalyzed Ring-Closing Metathesis to Form Tetrasubstituted Olefins
- 1 March 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (7) , 1339-1342
- https://doi.org/10.1021/ol070194o
Abstract
Increased efficiency for ring-closing metathesis to form tetrasubstituted olefins using N-heterocyclic carbene ligated ruthenium catalysts was achieved by reducing the size of the substituents at the ortho positions of the N-bound aryl rings.Keywords
This publication has 16 references indexed in Scilit:
- Latent Olefin Metathesis Catalysts Featuring Chelating AlkylidenesOrganometallics, 2006
- Highly Active Chiral Ruthenium Catalysts for Asymmetric Cross‐ and Ring‐Opening Cross‐MetathesisAngewandte Chemie International Edition in English, 2006
- A Standard System of Characterization for Olefin Metathesis CatalystsOrganometallics, 2006
- Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium InteractionJournal of the American Chemical Society, 2006
- Highly Active Chiral Ruthenium Catalysts for Asymmetric Ring-Closing Olefin MetathesisJournal of the American Chemical Society, 2006
- Prevention of Undesirable Isomerization during Olefin MetathesisJournal of the American Chemical Society, 2005
- Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis ReactionsJournal of the American Chemical Society, 2004
- Synthesis, Structure, and Activity of Enhanced Initiators for Olefin MetathesisJournal of the American Chemical Society, 2003
- Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene LigandJournal of the American Chemical Society, 1999
- A Novel Class of Ruthenium Catalysts for Olefin MetathesisAngewandte Chemie International Edition in English, 1998