Absence of asymptotic-time symmetry breaking in a symmetric double-well model of the H-bond with damped stretching mode
- 1 February 1991
- journal article
- Published by EDP Sciences in Journal de Physique I
- Vol. 1 (2) , 235-239
- https://doi.org/10.1051/jp1:1991126
Abstract
The proof is given that in a symmetric double well model of symmetric H-bond with damped stretching mode, there is no asymptotic-time symmetry breaking owing to a full initial asymmetry of the proton localization. So, in a correspondence with the ergodic hypothesis, the final proton distribution deduced from the kinetic treatment is the same in both wells as predicted by the equilibrium statistical mechanicsKeywords
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