Complex-forming reactions of an arylcopper(I) cluster compound with organophosphines. An unexpected C(alkyl)–P bond cleavage in 1,2-bis(diphenylphosphino)ethane
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 452-453
- https://doi.org/10.1039/c39720000452
Abstract
Whereas the 1 : 1 reaction of (2-cupriobenzyl)dimethylamine (RCu) with 1,2-bis(diphenylphosphino)ethane (diphos) affords the 1 : 1 complex RCu(diphos), 1 : 2 reaction results in cleavage of the C(alkyl)–P bond with formation of Ph2PCu(diphos)(solv), RH, and Ph2PCH = CH2.Keywords
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