Spectra of chloroferrate(III) compounds
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 723-725
- https://doi.org/10.1039/j19660000723
Abstract
Improved ultraviolet, visible, and infrared spectra and Mössbauer studies clearly indicate that [Ge(acac)3][FeCl4], [Ti(acac)3][FeCl4], [Si(acac)3][FeCl4], and [Zr(bzbz)3][FeCl4](where acac = acetylacetone and bzbzH = dibenzoylmethane) contain the tetrachloroferrate(III) species both in solution and in the solid state. The Mössbauer spectra of [Co(NH3)6][FeCl6] and [Co(en)3][FeCl6] are distinguishable from those of compounds containing the [FeCl4 –] anion.Keywords
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