An easy access to enantio-enriched α-substituted aldehydes by carbolithiation of β-phenyl or β-silyl-α,β-ethylenic aldehydes, protected with the monolithioamide of a chiral diamine
- 1 March 2001
- journal article
- research article
- Published by Elsevier in Tetrahedron Letters
- Vol. 42 (10) , 1883-1885
- https://doi.org/10.1016/s0040-4039(01)00034-x
Abstract
No abstract availableThis publication has 9 references indexed in Scilit:
- Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes— Configurational Stability of Benzylic Organozinc HalidesChemistry – A European Journal, 1999
- Regioselective addition ofnbutyllithium on secondary cinnamyl amides: “Michael" versus “contra-Michael" processTetrahedron Letters, 1999
- Diastereoselective “contra-Michael" addition of(−)-sparteineorganolithiumcomplexes to secondary chiral cinnamyl amidesTetrahedron Letters, 1999
- 3-Aminopyrrolidine lithium amide in enantioselective addition of organolithium compounds onto aromatic aldehydesTetrahedron: Asymmetry, 1997
- Enantioselective ortho-lithiation of benzaldehyde chromiumtricarbonyl complexTetrahedron: Asymmetry, 1995
- Chiral Diamines for a New Protocol To Determine the Enantiomeric Composition of Alcohols, Thiols, and Amines by 31P, 1H, 13C, and 19F NMRThe Journal of Organic Chemistry, 1994
- The Synthetic Utility of α-Amino AlkoxidesSynlett, 1992
- A Remarkable Effect of a 3-OLi Group to Fix the Conformation of Lithium 1-Phenyl-1-propanidesSynlett, 1990
- Model studies for the synthesis of quassinoids. 1. Construction of the BCE ring systemThe Journal of Organic Chemistry, 1980