Novel backbone rearrangement of steroids: formation of (20R and 20S) 1β,14β-dimethyl-18,19-dinor-5β,8α,9β,10α-cholest-13(17)-enes
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 133-135
- https://doi.org/10.1039/c39890000133
Abstract
Two new 1-methyl rearranged sterenes were formed from cholestan-3β-ol and related compounds by a novel backbone reaction, catalysed by K10-montmorillonite; their structures were determined by 1H and 13C n.m.r. spectroscopy.Keywords
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