Concerted and non-concerted transformations of cyclopropyl to allyl; the solvolysis of endo- and exo-7-chloro-7-p-substituted-phenylbicyclo[4,1,0]heptanes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 868b-870
- https://doi.org/10.1039/c2969000868b
Abstract
Activation parameters have been obtained for the acetolysis of epimeric 7-chloro-7-p-substitutedphenylbicyclo[4,1,0]heptanes; the evidence suggests concerted dis(2) and non-concerted dis(0) modes of ring opening for the endo- and exo-chloro-epimers, respectively.Keywords
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