A new cyclam with an appended imidazole. The first biomimetic ligation of imidazole for axial π-interaction with metal ions
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1712-1714
- https://doi.org/10.1039/c39870001712
Abstract
A new cyclam functionalised with a pendant imidazole (4) is reported; the X-ray crystal structure of its NiII complex (6) shows the most appropriate orientation of the imidazole for axial π-interaction with metal ions.Keywords
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