Semiclassical shape of satellite bands: Application to CsAr
- 1 March 1974
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 9 (3) , 1103-1107
- https://doi.org/10.1103/physreva.9.1103
Abstract
A term representing interference between classical paths is isolated from the previously derived equation for the semiclassical shape of satellite bands. A band shape quantitatively accurate in the adiabatic one-perturber approximation is given by addition of the classicalpath contributions to the interference term. Comparison is made to a quantum-mechanical calculation of a satellite band in the red wing of the self-broadened Lyman- line of hydrogen and to an experimentally observed band in the blue wing of the cesium 8521- resonance line perturbed by argon. The problem of inversion to determine a difference potential from the observed band shape is discussed.
Keywords
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