New Ammonia Equivalents for the Pd-Catalyzed Amination of Aryl Halides
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- 26 September 2001
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 3 (21) , 3417-3419
- https://doi.org/10.1021/ol0166808
Abstract
LiN(SiMe3)2, Ph3SiNH2, and LiNH2 can be be used as ammonia equivalents for the Pd-catalyzed coupling of aryl halides. Using these amine derivatives, simple anilines, including ortho-substituted ones, as well as di- and triarylamines can be readily prepared.Keywords
This publication has 1 reference indexed in Scilit:
- Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C−N Bond Formation with a Commercial LigandThe Journal of Organic Chemistry, 1999