Synthesis and X-ray crystal structure of a C-spiro-bi-[cyclam nickel(II)] complex (cyclam = 1,4,8,11-tetra-azacyclotetradecane)
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 539-541
- https://doi.org/10.1039/c39870000539
Abstract
The salt 6,6′-spirobi[1,4,8,11-tetra-azacyclotetradecane]nickel(II) tetraperchlorate {C-spiro-bi-[cyclam nickel(II)]} was isolated as single crystals and the X-ray crystal structure obtained; a deviation in orthogonality of the macrocyclic rings, resulting in possible Ni–Ni interaction, is deduced from the e.s.r. spectra of the oxidised forms of the complex.Keywords
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