The Lattice Energy of Solid CO2
- 1 September 1937
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 5 (9) , 745-751
- https://doi.org/10.1063/1.1750110
Abstract
It is possible to account for the measured sublimation heat of solid CO2 by calculating the attraction energy according to London's theory of van der Waals forces; or, when the second approximation of the attractive forces is included, by considering also the electrostatic energy due to the dipole moments and the repulsive energy, the latter being deduced from the equilibrium condition. For the calculation of the electrostatic energy the picture of point charges with definite distances seems preferable to that of short dipoles.Keywords
This publication has 14 references indexed in Scilit:
- The general theory of molecular forcesTransactions of the Faraday Society, 1937
- Dipole Moment and Structure of Organic Compounds. XVI.1 The Electric Moments of Some Chlorinated DiphenylsJournal of the American Chemical Society, 1936
- The van der Waals potential and the lattice energy of a n — CH 2 chain molecule in a paraffin crystalProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1936
- A New Approximation Method in the Problem of Many ElectronsThe Journal of Chemical Physics, 1935
- New determination of the lattice constant of carbon dioxidePhysica, 1934
- The Infrared Dispersion of Carbon DioxidePhysical Review B, 1932
- The Role of Quadrupole Forces in Van Der Waals AttractionsPhysical Review B, 1931
- The Van Der Waals Forces in GasesPhysical Review B, 1931
- Die Dispersion der Kohlensäure vom Ultravioletten bis ins UltraroteThe European Physical Journal A, 1928
- On the refraction and dispersion of carbon dioxide, carbon monoxide, and methaneProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1920