Stereoselective Synthesis of 2,3,5-Substituted Tetrahydrofurans by Silicon-Directed Cyclization of Allylsilanes Bearing a Hydroxy Moiety
- 1 October 1998
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1998 (10) , 1150-1152
- https://doi.org/10.1055/s-1998-1888
Abstract
Acid promoted cyclization of bishomoallylic alcohols bearing allylsilanes proceeded smoothly by way of β-silyl carbocation intermediate to furnish tetrahydrofurans highly stereoselectively.Keywords
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