Kinetics of fluorine atom reactions using resonance absorption spectrometry in the far vacuum ultraviolet reactions F + HCl, CH4, CHCl3 CHCl2F, and CHClF2
- 1 April 1978
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 10 (4) , 367-387
- https://doi.org/10.1002/kin.550100404
Abstract
Atomic resonance absorption spectrometry with a nonreversed fluorine resonance lamp (∼95 nm) has been used to study the kinetics of elementary reactions of ground state F2PJ atoms in a discharge‐flow system. The following rate constants (in cm3/molec·sec) All rate constants are given with 1.5 σ. were determined at 298° K: equation image The reaction F 2PJ + HCl(1) was found to give J‐excited Cl 2P1/2 atoms with a product branching ratio [Cl 2P1/2]/[Cl 2P3/2] = 0.10.Keywords
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