Preparation of Primary Alkylantimony Compounds
- 1 January 1978
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 8 (5-6) , 453-465
- https://doi.org/10.1080/00945717808057435
Abstract
In comparison with the lighter group-V elements, access to primary alkyl compounds of antimony [containing either RSb(III) or RSb(V)] is impeded by the low thermal stability of the hydrides, RSbH2, and the puzzling non-existence of alkylstibonic acids, RSbO(OH)2. Existing procedures for the preparation of RSbX2 (X = halogen) frequently yield products which are difficult to separate and often have limited general application. New synthesis procedures and improvements in earlier procedures are describedKeywords
This publication has 14 references indexed in Scilit:
- An NMR study of the reactions of primary alkylphosphines, arsines and stibines with disulfur dichlorideInorganica Chimica Acta, 1978
- Reactions of alkylphosphorus, arsenic, and antimony hydrides and halides with dibenzylmercury. An improved procedure for cyclopolyarsinesJournal of Organometallic Chemistry, 1977
- Investigations on organoantimony compoundsJournal of Organometallic Chemistry, 1972
- Reactions of some trialkyls of phosphorus, arsenic, or antimony with some organohalophosphines, -arsines, or -stibinesInorganic Chemistry, 1970
- Infrared and hydrogen-1 nuclear magnetic resonance spectra of the methylstibinesInorganic Chemistry, 1968
- Exchange of Parts between Molecules at Equilibrium. IX. Kinetics and Mechanisms for the Scrambling of Two Substituents on a Central AtomJournal of the American Chemical Society, 1966
- The direct synthesis of organoarsenic and organoantimony compoundsJournal of Inorganic and Nuclear Chemistry, 1961
- The Methylstibines and the Monomer DimethylstibinoborineJournal of the American Chemical Society, 1959
- ALKYLATION REACTIONS OF TETRAETHYLLEAD. A NEW SYNTHESIS OF ETHYLDICHLOROARSINE AND RELATED COMPOUNDS1The Journal of Organic Chemistry, 1949
- Antimonial analogues of the cacodyl seriesProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1926