Co-condensation of molybdenum atoms with the bulky tertiary diphosphine 1,2-bis(di-isopropylphosphino)ethane: the molecular structure of [MoH4(Pri 2PCH2CH2PPri 2)2]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 8,p. 2227-2229
- https://doi.org/10.1039/dt9880002227
Abstract
Co-condensation of molybdenum atoms with the tertiary diphosphine 1,2-bis(di-isopropylphosphino)ethane affords the stereochemically non-rigid, eight-co-ordinate tetrahydride complex [MoH4(Pri 2PCH2CH2PPri 2)2]. The crystal structure has been determined in the orthorhombic space group Ccca(no. 68), with cell parameters a= 18.351(2), b= 20.164(2), c= 9.150(6)Å, and Z= 4.Keywords
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