A biomimetic synthesis of the novel 6,7-oxazine ring-fused dehydroaporphine alkaloid duguenaine

Abstract
A biomimetically patterned synthesis of the novel oxazine-fused dehydronoraporphine alkaloid, duguenaine, which proceeds in three steps from an isoquinoline enamide has been developed. The reactions leading to the natural product are general and yield equivalent structures with more highly substituted dehydronoraporphines.

This publication has 0 references indexed in Scilit: