Molecular Formulation of Thermodynamic Functions Encountered in Solution Theory

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Abstract
The general statistical mechanical formulation of partial molar energies, ``internal pressure,'' and heat capacity of multicomponent systems is developed with use of the grand ensemble. In the case of two component systems, detailed concentration expansions are presented for partial molar free energies and energies and for radial distribution functions about standard states at constant temperature and pressure as well as constant temperature and partial molar volume.

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