Notizen: Kristall- und Molekülstruktur von Bis (trimethylsilyl)amino-trimethylsilyliminophosphin bei —130 °C / Crystal and Molecular Structure of Bis (trimethylsilyl)amino-trimethylsilyliminophosphine at —130 °C
Open Access
- 1 November 1977
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (11) , 1344-1345
- https://doi.org/10.1515/znb-1977-1125
Abstract
The crystal structure of R2N–P=NR (R = Si(CH3)3) was determined by single crystal X-ray data collected at —130 °C and refined to a conventional R-value of 0.029. The structure exhibits a two-connected phosphorus atom. The short P = N multiple bond (154.5 pm) indicates a 3pπ(P)—2pπ(Ν) interaction. The N–P–N angle was found to be 108.4°.Keywords
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