Synthesis of hydrido-bis(acetylide) complexes of rhodium and the molecular structures of mer-trans-[Rh(PMe3)3(H)(CCPh)2] and mer-trans-[{Rh(dmpe)(H)(CCSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2)
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1545-1547
- https://doi.org/10.1039/c39890001545
Abstract
Complexes of the form mer-trans-[Rh(PMe3)3(H)(CCR)2] and mer-trans-[{Rh(dmpe)(H)(CCR)2}2(µ-dmpe)] have been prepared by oxidative addition of HCCR to [Rh(PMe3)4(CCR)] and [Rh(dmpe)2Me] species, respectively; the molecular structures of mer-trans-[Rh(PMe3)3(H)(CCPh)2] and mer-trans-[{Rh(dmpe)(H)(CCSiMe3)2}2(µ-dmpe)](dmpe = Me2PCH2CH2PMe2) have been determined by single crystal X-ray diffraction studies.Keywords
This publication has 0 references indexed in Scilit: