Bisphosphonic Compounds. II. Preparation of Monophosphonic Starting Materials. Mixed Esters of Methylphosphonic Acid
- 1 January 1992
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 22 (2) , 271-276
- https://doi.org/10.1080/00397919208021302
Abstract
Methyl (1-methylelhyl) methylphosphonate was obtained from PCI3 via (PriO)PCI2 and (PriO)P(OMe)2 followed by the Michaelis-Arbuzov reaction with Mel. The yield was 79% with 95% chemical purity. Less reasonable conversions were obtained for some related mixed diesters.Keywords
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