Spin-Ising model for tricritical points in ternary fluid mixtures
- 1 January 1975
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 11 (1) , 399-410
- https://doi.org/10.1103/physrevb.11.399
Abstract
We present a lattice-gas model of ternary fluid mixtures. Within the mean-field approximation, we study a nonsymmetric tricritical point in this model. We compare our results to the experimental observations on the system ethanol-water-carbon-dioxide. In the course of our work, we have studied a Landau theory describing the neighborhood of a fourth-order critical point. Also, we have noted that mean-field theory indicates the existence of a fourth-order critical point in the spin-1 model of Blume, Emery, and Griffiths, corresponding to , .
Keywords
This publication has 11 references indexed in Scilit:
- Ising model for tricritical points in ternary mixturesPhysical Review A, 1974
- Thermodynamic model for tricritical points in ternary and quaternary fluid mixturesThe Journal of Chemical Physics, 1974
- Tricritical points in three- and four-component fluid mixturesThe Journal of Physical Chemistry, 1973
- Phase Transitions Due to Softness of the Potential CoreThe Journal of Chemical Physics, 1972
- Dipolar and Quadrupolar Ordering inIsing SystemsPhysical Review B, 1972
- Ising Chain with Several Phase TransitionsThe Journal of Chemical Physics, 1971
- Ising Model for theTransition and Phase Separation in-MixturesPhysical Review A, 1971
- Inequalities of J. W. GibbsAmerican Journal of Physics, 1970
- Thermodynamics Near the Two-Fluid Critical Mixing Point in-Physical Review Letters, 1970
- A Proof that the Free Energy of a Spin System is ExtensiveJournal of Mathematical Physics, 1964