Protonation of [{MnIV(saltn)(µ-O)}2] results in significant modification of structure and catalase-like reactivity
- 1 January 1992
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 102-103
- https://doi.org/10.1039/c39920000102
Abstract
Protonation of an {MnIV(µ2-O)}2 core to form {(MNIV)2(µ2-O)(µ2-OH)} leads to perturbations of the physical properties of this unit including an increase in metal–metal separation (ca. 0.1 Å) and loss of catalase reactivity.Keywords
This publication has 15 references indexed in Scilit:
- The peroxide-dependent .mu.2-O bond formation of manganese complex [Mn(IV)SALPN(O)]2Journal of the American Chemical Society, 1991
- Proton-coupled electron transfer in high-valent oxomanganese dimers: role of the ancillary ligandsInorganic Chemistry, 1991
- Binuclear bis(.mu.-oxo)dimanganese(III,IV) and -(IV,IV) complexes with N,N'-bis(2-pyridylmethyl)-1,2-ethanediamineInorganic Chemistry, 1990
- Proton-coupled electron transfer in manganese complex [(bpy)2Mn(O)2Mn(bpy)2]3+Journal of the American Chemical Society, 1989
- Crystal structure and magnetic susceptibility of the dinuclear manganese(IV) complex Mn2O2(pic)4.cntdot.MeCN (picH = picolinic acid)Inorganic Chemistry, 1989
- The Active Sites in Manganese‐Containing Metalloproteins and Inorganic Model ComplexesAngewandte Chemie International Edition in English, 1989
- Structural and electronic consequences of protonation in {Mn4O6}4+ cores: pH dependent properties of oxo-bridged manganese complexesJournal of the American Chemical Society, 1989
- Biological Exploitation of Solar Energy by Photosynthetic Water SplittingAngewandte Chemie International Edition in English, 1987
- Ab initio calculations of amplitude and phase functions for extended x-ray absorption fine structure spectroscopyJournal of the American Chemical Society, 1979
- Novel antiferromagnetic oxo-bridged manganese complexJournal of the American Chemical Society, 1972