‘Capped’ tri-ruthenium carbonyl cluster: X-ray crystal structure of [Ru3(CO)9{MeSi(PBu2)3}]
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1005-1006
- https://doi.org/10.1039/c39780001005
Abstract
The tridentate tertiary-phosphine ligand MeSi(PBu2)3 reacts with Ru3(CO)12 in refluxing benzene to give the symmetrical complex [Ru3(CO)9{MeSi(PBu2)3}], containing three bridging carbonyl ligands and one phosphorus centre co-ordinated to each of the ruthenium atoms as shown by X-ray crystallography.Keywords
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