Heterobimetallic clusters of copper(I) with [MS42–](M = Mo, W). Synthesis and structural characterization of polymeric (NMe4)2[(CuNCS)4WS4]
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1557-1558
- https://doi.org/10.1039/c39860001557
Abstract
Reaction of (NMe4)2WS4 with CuCl and KSCN (1 : 2 : 2) in CH3CN–CH2Cl2(1 : 1) produces the bimetallic sulphur anion; a crystal structure determination shows that four edges of the WS4Cu4 core are –NCS–bridged giving a three-dimensional polymer.Keywords
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