Oxidative N-demethylation of N,N-dimethylanilines catalysed by lignin peroxidase: a mechanistic insight by a kinetic deuterium isotope effect study

Abstract
Lignin peroxidase can catalyse the N-demethylation of N,N-dimethylanilines by an electron transfer mechanism, where the deprotonation of the intermediate radical cation is also an enzymatic process.

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