Abstract
The following triply 15N labelled azides CH3N3, C6H5N3, O2NC6H4N3, (O2N)3C6H2N3, NCN3, and (NCN3)3 were investigated by 15N NMR and partially by vibrational and 13C NMR specrtoscopy. The signals of the β- and γ-N atom show an overcrossing. 1J(15N -13C) is zero for the arylazides.

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