Heterolytic H2 Activation by Dihydrogen Complexes. Effects of the Ligand X in [M(X)H2{Ph2P(CH2)3PPh2}2]n+ (M = Ru, Os; X = CO, Cl, H)
- 12 February 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 36 (4) , 711-720
- https://doi.org/10.1021/ic9605579
Abstract
No abstract availableKeywords
This publication has 57 references indexed in Scilit:
- Protonation of Metal Hydrides by Strong Acids. Formation of an Equilibrium Mixture of Dihydride and Dihydrogen Complexes from Protonation of Cp*Os(CO)2H. Structural Characterization of [CpW(CO)2(PMe3)(H)2]+OTf−Organometallics, 1996
- Synthesis, Structure, and Properties of the Stable and Highly Acidic Dihydrogen Complex trans-[Os(η2-H2)(CH3CN)(dppe)2](BF4)2. Perspectives on the Influence of the trans Ligand on the Chemistry of the Dihydrogen LigandOrganometallics, 1996
- Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of OsmiumInorganic Chemistry, 1996
- Cationic Hydrogen Complexes of RheniumJournal of the American Chemical Society, 1994
- [Os(.eta.2-H2)(CO)(pyS)(PPh3)2]BF4-a stable but highly acidic dihydrogen complexOrganometallics, 1993
- Coordination chemistry of dihydrogenChemical Reviews, 1993
- Reactions of transition metal dihydrogen complexesCoordination Chemistry Reviews, 1992
- Ligand additivity effects and periodic trends in the stability and acidity of octahedral .eta.2-dihydrogen complexes of d6 transition metal ionsInorganic Chemistry, 1992
- Kinetics and mechanism of catalysis of the asymmetric hydrogenation of .alpha.,.beta.-unsaturated carboxylic acids by bis(carboxylato) {2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}ruthenium(II), [RuII(BINAP) (O2CR)2]Journal of the American Chemical Society, 1991
- C–H and H–H bond activation; dissociative vs. nondissociative binding to iridiumJournal of the Chemical Society, Chemical Communications, 1985