Synthesis of ecdysone.II.Synthesis of and Stereochemistry of 2β, 3β-Dihydroxycholestan-6-ones and Their Derivatives
- 1 January 1967
- journal article
- research article
- Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN
- Vol. 15 (4) , 466-473
- https://doi.org/10.1248/cpb.15.466
Abstract
2[beta],3[beta]-Dihydroxycholestan-6-ones and their derivatives were prepared and their stereochemistry was studied. In 2/3,3/3-dihydroxy- or 2[beta],3[beta]-diacetoxycholestan-6-ones, equilibrium mixture consisted of 5[alpha]- and 5[beta]-compound at the ratio of 3:2. The 5a-compound was found to be exclusively stable in 2[beta],3[beta]-dihydroxycholestan-6-one acetonides.This publication has 1 reference indexed in Scilit:
- Synthesis of Exdysone.I.A Novel Synthesis of 2β, 3β-Dihydroxy SteroidsCHEMICAL & PHARMACEUTICAL BULLETIN, 1967